Ionic Liquids. Industrial Applications for Green Chemistry by Robin D. Rogers and Kenneth R. Seddon (Eds.)
By Robin D. Rogers and Kenneth R. Seddon (Eds.)
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These solvents are often fluid at room temperature, and commonly consist of organic cationic species and inorganic anionic species; they have no measurable vapor pressure, and hence can emit no Volatile Organic Compounds (VOCs). ; ACS Symposium Series; American Chemical Society: Washington, DC, 2002. ch003 One indication of the growth in interest in these compounds is shown by the increase in the number of articles on this topic during a ten-year period. (Figure 1) The current year is only half over!
In BPC/A1C1 the isomerizations occur through stilbene radical cations. The one-component, non-volatile bmimPF is useful i n organoborane chemistiy. The tributylborane induced reduction of aldehydes occurs at temperatures far lower than seen i n other solvents. The Suzuki reaction occurring i n two green phases, K F / A 1 0 and bmimPF , are remarkably alike. ch004 2 3 6 Experimental Section Diels-Alder Reactions. The Diels-Alder reactions were run i n the absence of solvent (neat) or i n Dimcarb using a 1:1 molar ratio of cyclopentadiene and dienophile.
J. Chem. 2000, 6, 1017. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2002. ch002 29 24. Brasse, C. ; Salzer. ; Wasserscheid, P. ; Waffensclirnidt, H. J. Mol. Catal. , 2000, 164, 61-67 25. Abdul-Sada, A. ; Atkins, M . ; Hodgson, P. K. ; Morgan, M . L. M . ; World Patent WO9521806, 1995; Chauvin, Y ; Commereuc, D; Hirschauer, A; Hugues, F; Saussine, L; French Patent FR 2,626,572, 1989. 26. Adams, C. ; Earle, M . ; Roberts, G; Seddon, K. R. Chem. , 1998, 2097-2098. 27. Howarth, J.