CRC Handbook of Fundamental Spectroscopic Correlation Charts by T. Bruno, P. Svoronos

By T. Bruno, P. Svoronos

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62 Notes: Moderately polar, weakly hydrogen-bonding solvent, dense liquid; gradually decomposes to acquire a yellow color, with air and/or light accelerating this decomposition; nonflammable; commercial product is often stabilized by the addition of 3–4% (mass/mass) alcohols; highly toxic by ingestion, inhalation, and skin absorption; soluble in alcohols, organohalogen compounds, hydrocarbons, benzene, and many oils. Incompatible with many alkali and alkaline earth metals. Synonyms: tribromomethane.

10. , The properties of organic liquids that are relevant to their use as solvating solvents, Chem. Soc. , 22(6): 409–416, 1993. 75 Forms azeotrope with water (at 16% mass/mass) that boils at 76°C. Notes: Highly polar solvent; sweet, ethereal odor; soluble in water; flammable, burns with a luminous flame; highly toxic by ingestion, inhalation, and skin absorption; miscible with water, methanol, methyl acetate, ethyl acetate, acetone, ethers, acetamide solutions, chloroform, carbon tetrachloride, ethylene chloride, and many unsaturated hydrocarbons; immiscible with many saturated hydrocarbons (petroleum fractions); dissolves some inorganic salts such as silver nitrate, lithium nitrate, magnesium bromide; incompatible with strong oxidants; hydrolyzes in the presence of aqueous bases and strong aqueous acids.

W. , Dimethyl sulfoxide oxidations, Chem. Rev. 67(3): 247–260, 1967. 7. , CRC Press, Boca Raton, Fl, 2003. 8. J. , CRC Press, Boca Raton, FL, 2003. 9. NIST, NIST Chemistry Web Book, NIST Standard Reference Database, No. 69, March 2003. gov/chemistry. 10. , The properties of organic liquids that are relevant to their use as solvating solvents, Chem. Soc. , 22(6): 409–416, 1993. 75 Forms azeotrope with water (at 16% mass/mass) that boils at 76°C. Notes: Highly polar solvent; sweet, ethereal odor; soluble in water; flammable, burns with a luminous flame; highly toxic by ingestion, inhalation, and skin absorption; miscible with water, methanol, methyl acetate, ethyl acetate, acetone, ethers, acetamide solutions, chloroform, carbon tetrachloride, ethylene chloride, and many unsaturated hydrocarbons; immiscible with many saturated hydrocarbons (petroleum fractions); dissolves some inorganic salts such as silver nitrate, lithium nitrate, magnesium bromide; incompatible with strong oxidants; hydrolyzes in the presence of aqueous bases and strong aqueous acids.

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